I have 2005 XC70 with a similar issue - except it's only the offside rear door that does what the OP describes - locks the door intermittently - in other words, not always.
I can't find any pattern to when this is happening - just now and then.
I unlock it from the driver's door lock/unlock switch and it unlocks and when opened and then closed it may - or may not lock.
Puzzling.
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2008 XC70 D5 Lux Geartronic Polestar, 161K
2005 XC70 D5 SE Geartronic, 203K
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