Sitting for a week would not bother a healthy car and battery.... sitting for 3 months maybe....
With regard to MOT emission, if it is normally driven gently then an "Italian tune up" will probably sort it, do half a dozen runs from say 20 to 60 with your foot to the floor.
Wife used to have a Kia Ceed and had the same problem, a good thrashing later it was fine. Carbon in the exhaust can get loosened on the fast acceleration run and cause a higher reading on the opacity meter.
Or the garage is trying it on....
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2011 XC90 D5 Executive
2003 C70 T5 GT
2012 Ford Ranger XL SC
1977 Triumph Spitfire 1500
1976 Massey Ferguson 135
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